Function addExpressionAttributeToSelect as defined in Mage_Eav_Model_Entity_Collection_Abstract (/app/code/core/Mage/Eav/Model/Entity/Collection/Abstract.php) allows us to use MySQL functions in Magento collection.
Here is an example of using MySQL function CONCAT in Magento customer collection to concat customer’s firstname and lastname:
$collection = Mage::getResourceModel('customer/customer_collection')
->addExpressionAttributeToSelect('fullname', 'CONCAT({{firstname}}, " ", {{lastname}})', array('firstname','lastname'));
Here is another example which uses MySQL function MONTH which fetches only month from customer’s birthdate.
$collection = Mage::getResourceModel('customer/customer_collection')
->addExpressionAttributeToSelect('birth_month', 'MONTH({{dob}})', 'dob')
->joinAttribute('dob', 'customer/dob', 'entity_id', null, 'left');
Hope it helps. Thanks.